Shibayama, Mitsuhiro
Professor
solid state physics
University of Tokyo
Japan
Biography
Soft matter undergoes various transitions in response to a slight change of an environmental variable. We investigate the relationship of the structure and dynamics of soft matter, such as polymer gels, nanoemulsion, and micelles. The aims of our research are systematization of “molecular-bond correlated systems”. Concurrently, we explore various applications of soft matter on the basis of the physics of soft matter. Nano-order structure investigations and studies on dynamics of soft matter are carried out with state-of-the-art equipments, SANS-U, a small-angle neutron scattering instrument (upgraded in 2010). Other techniques, such as dynamic/static light scattering, microscopy, mechanical/thermal analyses, and rheological studies, are also employed. Current interests cover (1) inhomogeneities in polymer gels, (2) structural characterization and studies on deformation mechanisms of high-performance polymer gels, (3) rheo-SANS of nanoemulsion and micelles, and (4) development of ion-gel and structural analyses, (5) fabrication of uniform-polymer networks and their structure/property characterization, (6) development of high-performance thermoset polymers by structure-designing and molecular dynamics simulations.
Research Interest
Structure and physical properties of uniform polymer gels Development of ion gels and structural characterization Structure formation and rheological properties of multi-arm surfactant assemblies in aqueous solutions Structural analyses and molecular dynamics simulation of thermoset polymers
Publications
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†Microscopic Structure of the “Nonswellable†Thermoresponsive Amphiphilic Conetwork: S. Nakagawa, X. Li, H. Kamata, T. Sakai, E. P. Gilbert and M. Shibayama, Macromolecules 50 (2017) 3388.
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Decisive test of the ideal behavior of tetra-PEG gels: F. Horkay, K. Nishi and M. Shibayama, J. Chem. Phys. 146 (2017) 164905(1)-164905(8).
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Structure-mechanical property relationships in crosslinked phenolic resin investigated by molecular dynamics simulation: Y. Shudo, A. Izumi, K. Hagita, T. Nakao and M. Shibayama, Polymer 116 (2017) 506-514.